研究进展
广东省科技厅副厅长杨军一行莅临功能配位超分子材料及应用广东省重点实验室调研指导
2021-09-01
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2021年8月23日上午，广东省科技厅副厅长杨军、高新处处长张冬蕾、副处长郭秀强，广东省科技情报研究所副所长张佰尚一行莅临功能配位超分子材料及应用广东省重点...
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2020-03-25
High-efficiency perovskite solar cells based on self-assembly n-doped fullerene derivative with excellent thermal stability
50次浏览
1-s2.0-S0378775318314174-main.pdf
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2020-03-24
Di-μ-iodo-bis [(1, 10-phenanthroline-κ2N, N′) copper (I)] acetonitrile solvate
26次浏览
Xiao-Ping Zhou, Dan Li,* and Seik Weng NgAbstract:In the title complex, [Cu2I2(C12H8N2)2]C2H3N, two CuI atoms are bridged by two I atoms and each CuI atom is chelated by a 1,10-phenanthroline ligand to give four-coordinate tetrahedral geometry.文章链接：ActaCryst.20050511.pdf
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2020-03-24
Hydrothermal synthesis of copper complexes of 40-pyridyl terpyridine: From discrete monomer to zigzag chain polymer
25次浏览
Hua Feng, Xiao-Ping Zhou, Tao Wu, Dan Li,* Ye-Gao Yin, and Seik Weng NgAbstract:Seven copper complexes [Cu(L1)I2] (1), [Cu2(L1)2I2]2[Cu2(l-I)2I2] (2), [Cu(L2)I2] (3), [Cu2(L2)(l-I)I(PPh3)] (4), [Cu4(L2)2(l-I)2I2] (5),{[Cu(L2)I]2[Cu2(l-I)2I2]}n (6) and [Cu2(L2)(l-I)2]n (7) have been prepared by reactions of ligands: 40-(2-pyridyl)-2,20:60,200-terpyridine(L1) and 40-(3-pyridyl)-2,20:60,200-terpyridine (L2) with CuI in hydrothermal conditions, respectively. By alternating the oxidations states of t
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2020-03-24
Increasing Structure Dimensionality of Copper(I) Complexes by Varying the Flexible Thioether Ligand Geometry and Counteranions
23次浏览
Rong Peng, Dan Li,* Tao Wu, Xiao-Ping Zhou, and Seik Weng NgAbstract:This work focuses on the systematic investigation of the influences of pyrimidine-based thioether ligand geometries and counteranions on the overall molecular architectures. A N-containing heterocyclic dithioether ligand 2,6-bis-(2-pyrimidinesulfanylmethyl)pyridine (L1) and three structurally related isomeric bis(2-pyrimidinesulfanylmethyl)-benzene (L2-L4) ligands have been prepared. On the basis of the self-assembly of CuX (X
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2020-03-24
Two Polyknotted Topological Isomers of Copper(I) 3,5-Bis(4-pyridyl)pyrazolates
30次浏览
Shun-Ze Zhan, Dan Li,* Xiao-Ping Zhou, and Xin-Hui ZhouAbstract:Two unprecedented 3D polyknotted isomers, arisen from different linkage modes of SCN-, were obtained from 3,5-bis(4-pyridyl)- 1H-pyrazole (Hbppz) and CuSCN under different conditions.文章链接：ic061152j.pdf
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2020-03-24
From large 3D assembly to highly dispersed spherical assembly: weak and strong coordination mediated self-aggregation of Au colloids
22次浏览
Xuanjun Zhang, Dan Li* and Xiao-Ping ZhouAbstract:Distinctly different 3D assemblies of B1.6 nm Au nanoparticles are constructed based on weak and strong coordination strategies. Reduction of KAuCl4 with NaBH4 in the presence of newlysynthesized 4-(4-phenylmethanethiol)-2,20:60,20 0-terpyridine (1) yields functionalized Au nanoparticles which assemble in situ into large 3D aggregates via weak coordination between alkali metal ions and terpyridine attached to separated particles. These assemblies
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