研究进展
超分子配位化学研究所与香港大学合作取得重要研究进展
2021-12-15
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近日，暨南大学化学与材料学院，超分子配位化学研究所陆伟刚、周小平和李丹教授团队与香港大学何健教授合作在美国化学会旗舰期刊《美国化学会志》（J. Am. Chem....
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2020-03-26
Reversible Multiphase Transition in a BioMOF and Its Distinctive Luminescence Turn-On in Alcohol Vapor
34次浏览
Jian-Ping Bai,Yong-Liang Huang,Mo Xie, Yifang Zhao, Dong Luo, Yan Yan Li, Weigang Lu,* and Dan Li*ABSTRACT:Solvothermal reaction of zinc meso-tetra(4-carboxyphenyl)-porphyrin and 2,6-diaminopurine with zinc salt in DMF affords a threedimensional bioMOF (1-α). Its infinite rod-shaped building block features an alternation of octahedral Zn4O and paddle-wheel Zn2 clusters bridged by 2,6-diaminopurines. The paddle-wheel Zn2 cluster undergoes reversible transformation with half into quasi-paddle-whee
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2020-03-26
Designing bioresponsive metal azolate framework-based nanosystem for efficient cancer therapy
31次浏览
Chengcheng Sang1, Li Ma1, Dong Luo, Hongxing Liu, Dan Li⁎, Tianfeng Chen⁎
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2020-03-25
Exohedral Cuprofullerene: Sequentially Expanding Metal Olefin Up to a C60@Cu24 Rhombicuboctahedron
78次浏览
Shun-Ze Zhan,*†§ Guo-Hui Zhang,† Jing-Hong Li,† Jia-Li Liu,† Si-Hui Zhu,† Weigang Lu,‡ Ji Zheng,‡ Seik Weng Ng,^Dan Li*‡ABSTRACT:Exohedral cuprofullerenes with 6-, 12-, or 24-nuclearity were obtained by utilizing fluorocarboxylic/dicarboxylic acid under solvothermal conditions. The 24-nuclear molecule presents a C60@Cu24 core-shell structure with a rhombicuboctahedron Cu24 coated on the C60 core, representing the highest nuclearity in metallofullerene. The resultant complexes show an efficient a
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2020-03-25
Recent Progress on Exploring Stable Metal–Organic Frameworks for Photocatalytic Solar Fuel Production
38次浏览
Xu-Sheng Wang, Lan Li, Dan Li,* and Jinhua Ye*ABSTRACT:Solar energy, a clean and sustainable energy source, can be harvested and converted to solar fuel to meet the ever-increasing energy demand. Integrating the photosensitizers and active catalytic sites into a single solid, metal–organic framework (MOF) with high void architectures and tunable chemical struc- tures, is proposed as a promising platform for photocatalysis. However, compared with the traditional inorganic photocatalysts, the phot
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2020-03-25
Guest effects on crystal structure and phosphorescence of a Cu6L3 prismatic cage
37次浏览
Zhi-Chun Shi,ab Wei Chen,b Shun-Ze Zhan, b Mian Li, b Mo Xie,a Yan Yan Li,aSeik Weng Ng,c Yong-Liang Huang, a Zhiyin Zhang,a Guo-Hong Ning *a and Dan Li *aABSTRACT:Coordination cages with a nanocavity can encapsulate various guests, which allows modulation of the physical and chemical properties of the host–guest inclusion complexes. In this work, we designed and prepared a phosphorescence Cu6L3 trigonal prismatic cage, which accommodates a series of aromatic guest molecules. Single crystal X-ra
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2020-03-25
A pH-regulated ratiometric luminescence Eu-MOF for rapid detection of toxic mycotoxin in moldy sugarcane
36次浏览
Yifang Zhao, a Heng Zeng,aKun Wu,aDong Luo,aXiao-Wei Zhu, aWeigang Lu * and Dan Li *ABSTRACT:Dual-emitting MOF materials have been widely explored in recent years for their potential applications as ratiometric luminescent probes. However, most of these dichromatic MOFs were constructed through encapsulation of dye molecules, and ones with intrinsic dual-emission from ligands and/or metal ions are still rare. Herein, we report a novel Eu-MOF (1) composed of trinuclear europium clusters and 2,6-n
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