研究进展
化学与材料学院与广东盈华电子科技有限公司 签订校企战略合作和教育实训基地协议
2021-12-03
16
11月30日，暨南大学化学与材料学院与广东盈华电子科技有限公司（以下简称盈华电子）校企战略合作及共建教育实训基地签约仪式在梅州市城北镇人民政府举行。暨南大...
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2020-03-25
Coordination disk-type nano-Saturn complexes
43次浏览
Shun-Ze Zhan,*acJing-Hong Li,aGuo-Hui Zhang,aMing-De Li,aShanshan Sun,aJi Zheng,bGuo-Hong Ning,bMian Li,aDai-Bin Kuang,dXu-Dong Wangd and Dan Li*bThe first coordination disk-type nano-Saturn complexes, [Cu10-(Mim)10]⊃C60and [Cu10(Mim)10]⊃C70(Mim=2-methylimidazolate),were assembled under one-pot solvothermal conditions. The highestnumber of 30 C–H...πinteractions between the [Cu10(Mim)10] disk andthe C60/C70 surfaces drives the formation of the nano-Saturns. Thecalculated interaction energy is mu
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2020-03-25
Twelve-Connected Net with Face-Centered Cubic Topology: A Coordination Polymer Based on [Cu12(m4-SCH3)6]6+ Clusters and CN- Linkers
37次浏览
Dan Li,* Tao Wu, Xiao-Ping Zhou, Rui Zhou, and Xiao-Chun HuangAbstract:a novel microporous polymer containing aface-centered cubic (fcu) topological network with the highestconnectivity, based on a dodecanuclear copper(i) cluster as a twelve-connected node, was synthesized by a simultaneous redox, sulfurization, and self-assembly reaction under solvothermal conditions. The concept of using a cluster as a building block to construct high-connectivity networks is therefore feasible, and the reacti
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2020-03-25
Side Chain Induced Self-Assembly and Selective Catalytic Oxidation Activity of Copper(I)−Copper(II)‑N4 Complexes
40次浏览
Yun-Long Hou,* Yun-Lei Peng, Yingxue Diao, Jie Liu, Lizhuang Chen,* and Dan Li*ABSTRACT:Crystalline coordination architectures with coordinativelyunsaturated metal sites are of great importance for their attractive properties.Tunable side chains of the 4-formylimidazole here were employed for directingthe subcomponent self-assembly of (CuIIN4)2(CuII)2(1), {(CuIIN4)(CuII)2}n(2), and {L(CuII)2}n(3) under the same solvothermal conditions, giving thestructural diversity. The unique square-planar CuI
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2020-03-25
Dichlorobis(phenothiazine-κS)palladium(II)
25次浏览
Dichlorobis(phenothiazine-κS)palladium(II)Xuanjun Zhang, Dan Li,* Xiao-Ping Zhou and Seik Weng Ng3.jpgABSTRACT: In the title complex, [PdCl2(C12H9NS)2], the Pd atom lies on a center of inversion and is coordinated by two chloride anions and two S atoms from two phenothiazine ligands, forming a square-planar PdCl2S2 geometry. In the crystal structure, a one-dimensional polymer structure is constructed via N—H Cl and N—H N hydrogen bonds.文章链接：3.pdf
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2020-03-25
Chiral 3D Coordination Polymers Consisting of Achiral Terpyridyl Precursors: from Spontaneous Resolution to Enantioenriched Induction
43次浏览
Tao Zuo+, Dong Luo+, Yong-Liang Huang, Yan Yan Li, Xiao-Ping Zhou,* and Dan Li*[a]文章链接：chem.201905091.pdf
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2020-03-25
Revealing High-Lying Intersystem Crossing in Brightly Luminescent Cyclic Trinuclear CuI /AgI Complexes
43次浏览
ABSTRACT: The increased attention to luminescent copper(I) complexes, mostly mononuclear and dinuclear ones, in the past few years was mainly due to the new pathways establishedin the intersystem crossing (ISC) for highly effiffifficient singlet/triplet harvesting, which showedgreat potential in light-emitting devices. Governing the photophysical processes of planar cyclictrinuclear complexes is more challenging owing to the rich intra- and intermolecular metal−metalinteractions involved, but ne
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