Qiong Xiao, Yuan Wu, Mian Li, Michael O’Keeffe* and Dan Li*Abstract:The renowned aperiodic Boerdijk–Coxeter helix is identified, with a modified, periodic form, in a MOF named ROD-1 [formulated as Cd(L), H2L = (3,5-dimethyl-1H-(pyrazol-4-yl)-methylene)benzoic acid], which exhibits unusual gas adsorption behaviours attributed to guest–guest interactions, and also interesting structural dynamics responding to temperature variation and gas adsorption.文章链接：c6cc04912e.pdf

Yurui Xue, Jiaofu Li, Zheng Xue, Yongjun Li, Huibiao Liu, Dan Li, Wensheng Yang,*and Yuliang Li*Abstract:We have used a scalable and inexpensive method to prepare a catalyst comprising graphdiyne nanosheetsupported cobalt nanoparticles wrapped by N-doped carbon (CoNC/GD); this unprecedentedly durable electrocatalyst mediated the hydrogen evolution reaction (HER) with highly catalytic activity over all values of pH. The durability of the CoNC/GD structure was evidenced by the catalytic performanc

Zheng Xue, Hui Yang, Juan Gao, Jiaofu Li, Yanhuan Chen, Zhiyu Jia, Yongjun Li, Huibiao Liu,* Wensheng Yang,* Yuliang Li, and Dan LiAbstract:A new method of in situ electrically induced selfassembly technology combined with electrochemical deposition has been developed for the controllable preparation of organic/ inorganic core/shell semiconductor heterojunction nanowire arrays. The size of the interface of the heterojunction nanowire can be tuned by the growing parameter. The heterojunction nano

Alexander Schoedel, Mian Li, Dan Li, Michael O’Keeffe,* and Omar M. YaghiAbstract:Rod MOFs are metal−organic frameworks in which the metal-containing secondary building units consist of infinite rods of linked metal-centered polyhedra. For such materials, we identify the points of extension, often atoms, which define the interface between the organic and inorganic components of the structure. The pattern of points of extension defines a shape such as a helix, ladder, helical ribbon, or cylinder

Xiao-Liang Wang, Ji Zheng, Mian Li, Seik Weng Ng, Sharon Lai-Fung Chan and Dan Li*Abstract:In this work, two polymorphs and a pseudopolymorph of a trinuclear copper(I) pyrazolate complex, namely,[Cu(L-Br)]3 (L-Br = 4-(4-bromophenyl)-3,5-dimethylpyrazolyl), were isolated. One of them shows remarkable molecular shape curving, which is imposed by short intermolecular CuI−CuI interaction and parallelogram-like Br4 halogen bonding. These two sets of noncovalent interactions propagate along different

Yurui Xue, Yuan Guo, Yuanping Yi, Yongjun Li, Huibiao Liu, Dan Li, Wensheng Yang,* and Yuliang Li*Abstract:Here weshowthatahighefficient hydrogenevolutionreactionwhichwascarriedoutonthein-situgrowthofself-supportedcore-shellnanowiresarrayconsistingofgraphdiyneastheshellandCuasthecore onCufoams(Cu@GDNA/CF).Subjecttopotentialcyclingtreatmentin0.5MH2SO4, theCu@GDNA/CF exhibitshighlycatalyticactivityforhydrogenevolutionreactionwithanonsetoverpotentialof52mVand aTafelslopeof69mVdec
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