Qiong Xiao, Yuan Wu, Mian Li, Michael O’Keeffe* and Dan Li*

Abstract: The renowned aperiodic Boerdijk–Coxeter helix is identified, with a modified, periodic form, in a MOF named ROD-1 [formulated as Cd(L), H2L = (3,5-dimethyl-1H-(pyrazol-4-yl)-methylene)benzoic acid], which exhibits unusual gas adsorption behaviours attributed to guest–guest interactions, and also interesting structural dynamics responding to temperature variation and gas adsorption.

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