发表论文
Immobilizing Redox-Active Tricycloquinazoline into a 2D Conductive Metal–Organic Framework for Lit...
2022-03-28
64
Jie Yan, Yutao Cui, Mo Xie, Guo-Zhan Yang, De-Shan Bin,* and Dan Li*Abstract: Heteroaromatic-conjugated aromatic molecules have inspired numerous inte...
查看更多 >
2020-03-26
Self-Assembly of Copper Polypyridyl Supramolecular Metallopolymers to Achieve Enhanced Anticancer Efficacy
41次浏览
Lanhai Lai+, Dong Luo+, Ting Liu, Wenjie Zheng, Tianfeng Chen,* and Dan Li*[a]ABSTRACT:Self-assembled functional supramolecular metallopolymers have demonstrated application potential in cancer therapy. Herein, a copper polypyridyl complex was found able to selfassemble into a supramolecular metallopolymer driven by the intermolecular interactions, which could enhance the uptake in cancer cells through endocytosis, and thus effectively inhibiting tumor growth in vivo without damaging to the majo
>
2020-03-26
A luminescent edge-interlocked prismatic heteroleptic metallocage assembled through a ligand replacement reaction
31次浏览
Shun-Ze Zhan, *a Jing-Hong Li, aGuo-Hui Zhang, a Xiao-Wei Liu, aMian Li, aJi Zheng, bSeik Weng Ngcand Dan Li *bABSTRACT:A luminescent edge-interlocked heteroleptic metallocage based on Cu3(pyrazolate)3 was prepared through a ligand replacement reaction from a homoleptic metallocage and a new ligand. Its structure was confirmed by XRD and MALDI-TOF mass spectrometry. Theoretical calculations revealed the new ligand was evidently responsible for the bathochromic shift of the optimal excitation. Th
>
2020-03-26
The p-acidity/basicity of cyclic trinuclear units (CTUs): from a theoretical perspective to potential applications
32次浏览
Ji Zheng, Hu Yang, Mo Xie and Dan Li *ABSTRACT:Cyclic trinuclear units (CTUs) based on Au(I), Ag(I) and Cu(I) cations, featuring near planar nine-membered coordination rings, represent an important class of metal-organic p-acids/bases with highly adjustable p-acidity/basicity. Their superior p-acidity/basicity coupled with Lewis-acidic and metal···metal bonding sites offers excellent attraction for a wide range of acidic/basic species, and usually followed by noticeable changes of luminescence o
>
2020-03-26
Bifunctional Gyroidal MOFs: Highly Efficient Lewis Base and Lewis Acid Catalysts
31次浏览
Yan Yan Li+,[a]Tian-Ya He+,[a, b] Rui-Rong Dai,[a]Yong-Liang Huang,[a] Xiao-Ping Zhou,*[a] Tianfeng Chen,*[a] and Dan Li*[a]ABSTRACT:A family of gyroidal metal–organic frameworks (STUs) composited with transition metal ions and bi-imidazolate ligands (BIm) were prepared and applied as both Lewis base and acid catalysts. Benefiting from the intrinsic basicity of the ligands and the Lewis acidic sites of the open metal centres, the STUs materials show excellent catalytic activities as Lewis base f
>
2020-03-26
pH-Modulated luminescence switching in a Eu-MOF: rapid detection of acidic amino acids
40次浏览
Yifang Zhao, Meng-Yan Wan, Jian-Ping Bai, Heng Zeng, Weigang Luand Dan Li *ABSTRACT:Single-emission probes have demonstrated limited application in complex systems because the signal can be easily disrupted by many non-analyte factors. MOF-based luminescence sensors have been widely explored due to their structural abundance and tunability. Herein, we report a dual-emitting Eu-MOF (1), constructed by Eu(NO3)3and 2,6-naphthalenedicarboxylic acid (H2NDC), exhibiting a specific luminescence switchi
>
2020-03-26
Control over the synthesis of homovalent andmixed-valence cubic cobalt-imidazolate cages
31次浏览
Liang Liang,‡bDong Luo, ‡aTao Zuo,aXiao-Ping Zhou *aand Dan Li *ABSTRACT:A series of cubic cobalt-imidazolate cages have been successfully synthesized via subcomponent self-assembly in different solvents under solvothermal conditions. The homovalent CoII and mixed-valence CoIII,II-imidazolate cages are assembled with control over the mixed solvent ratio of N,N-diethylformamide/ethanol, respectively.文章链接：c9cc02083g.pdf
>
