Abstract:White-light emission with CIE (0.32, 0.34) was realized for an o-terphenyl (oTP) molecule in its Ag3[3,5-(CF3)2Pz]3(Pz = pyrazolate) sandwiching adduct, originating from the hybrid of fluorescence and sensitized long-afterglow phosphorescence of oTP. Density functional theory (DFT) and time-dependent DFT calculations revealed that heavy-atom effects of Ag play acrucial role in sensitization of the triplet of oTP, giving off its ultralong phosphorescence.文章链接：InorgChem201912516.pdf

Abstract: The SiF62− anions are in situ formed in the reactions of MF2(M = Cu2+, Zn2+, Ni2+, and Co2+) salts and nitrogen-containing ligands in borosilicate glass tubes under solvothermal conditions and then used to further construct a family of metal−organic frameworks (MOFs). This in situ reaction demonstrates a new and facile strategy for the fabrication of MOFs based on SiF62−.文章链接：InorgChem201912501.pdf

Astract: An anionic microporous metal-organic framework (1), featuring a combination of mononuclear and tetranuclear zinc clusters and a mix-and-match strategy of two different types of organic ligands, has been successfully constructed via a solvothermal reaction. Its luminescence can be exclusively quenched by acetone. In situ single-crystal X-ray diffraction studies reveal the specific acetone binding sites and the existence of multiple hydrogen bonds between acetone and the framework. Togeth

Abstract:Solvothermal reaction of adenine, 1,3,6,8-tetrakis-(p-benzoic acid)pyrene (H4TBAPy), and Zn(NO3)2 in DMF afforded a three-dimensional anionic bioMOF 1. It features onedimensional tubular channels with exposed Watson–Crick faces and nitrogen-rich purines, which endows 1 with multiple adsorption sites on its polar surface, translating into high selectivity of C2 hydrocarbons over C1. Moreover, an isostructural bioMOF 1-NH2 was synthesized by using 2-aminoadenine in place of adenine, resul

Astract:A family of polyhedral metal-imidazolate cages based on the flexible bi-imidazole ligand L and Cu2+ ions have been synthesized and characterized, featuring an unusual Cu10L8 bicapped square antiprism structure (or Johnson solids, J17) with an adaptable cavity. These metal–organic cages encapsulate anions, and they will expand or compress after they are filled with different-sized anions.文章链接：DaltonTrans201917713.pdf

Hong Cai a, Yong-Liang Huangb, Dan Li b,*ABSTRACT:Biological metal–organic frameworks (BioMOFs) are a new class of crystalline porous materials developed in the last decade that represent a subclass of metal–organic frameworks (MOFs). Biomolecules introduced as components of MOFs confer biological compatibility for this emerging type of material, thus providing new opportunities for applications in biology, medicine, and a variety of other fields. In this review, to focus on host–guest chemistry