Li Yu, Mian Li, Xiao-Ping Zhou, and Dan Li*

Abstract: Inorganic copper(I)/silver(I) halide/pseudohalide components are used to thread classical organic tetracationic macrocycles, cyclobis(paraquat-p-phenylene) and cyclobis(paraquat-4,4′-biphenylene), to construct crystalline inorganic−organic adducts, featuring an unprecedented hybrid polyrotaxane and several unusual hybrid pseudorotaxanes and sandwiches.

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