研究进展
2020-03-23
对称性破缺与世纪难题
20次浏览
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2020-03-23
非中心对称结构光电功能晶体材料
35次浏览
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2020-03-23
镧系金属-有机框架的光磁性质调控
22次浏览
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2020-03-23
Interfacial Engineering with Polymer Brushes: from Nanopatterning to Soft Electronics
31次浏览
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2020-03-22
腺嘌呤生物金属有机框架的配位化学及超分子识别
35次浏览
才红, 许丽丽, 李冕,李丹摘要：生物金属有机框架(biological metal-organic framework, BioMOF)是近十来年发展起来的一类新型晶态多孔材料, 它采用生物分子作为有机连接体, 本身具有优良的生物相容性, 为生物学和医学方面的应用提供新的机遇. 本文总结了腺嘌呤作为有机配体与金属离子组装形成BioMOF的配位化学和结构特点, 介绍带有开放Watson-Crick位点(open Watson-Crick site)的BioMOF及其主客体化学的研究, 并展望其在化学和生物领域中的前景。关键词：生物金属有机框架, 腺嘌呤, 开放Watson-Crick 位点, 主客体化学, 自适应化学文献链接：N972015-01431.pdf
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2020-03-22
Enhanced anti-cancer activities of a gold(III) pyrrolidinedithiocarbamato complex incorporated in a biodegradable metal-organic framework
24次浏览
Raymond Wai-Yin Sun,* Ming Zhang, Dan Li,* Mian Li, and AliceSze-Tsai WongAbstract:An anti-cancer active gold(III) pyrrolidinedithiocarbamato complex [(PDTC)AuIIICl2] (1) has been synthesized and characterized by means of X-ray crystallography. Compared to the pyrrolidinedithiocarbamate ligand itself,this gold(III) complex displays an up to 33-fold higher anti-cancer potency towards a panel of cancer cell lines including the cisplatin-resistant ovarian carcinoma cell line (A2780cis). As demonstr
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