Tian Wen, Mian Li, Xiao-Ping Zhou and Dan Li*Abstract:The solvothermal in situ double cycloaddition reaction of 2- cyanopyrimidine, Cu2O and NaN3 with aqueous ammonia additive generated a two dimensional copper(I) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4- triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-triazolate ligands.文章链接：c1dt10488h.pdf

Shun-Ze Zhan, Mian Li, Xiao-Ping Zhou, Dan Li* and Seik Weng NgAbstract:Reported herein are a pair of supramolecular pseudo-isomers, namely, (Cu3I3)(Cu3L3)2?H2O (1) and (Cu3I3)(Cu3L3)2 (2) (L =3-(4-pyridyl)-5-isobutyl-pyrazolate), both of which incorporate Cu3Pz3 (Pz = pyrazolate) and Cu3I3 clusters as luminophores. The two complexes show distinct yellow (570 nm) and orange(638 nm) emissions, which are ascribed to the formation of the excimer and exciplex involving the same or different copper(I

Shun-Ze Zhan, Mian Li, Xiao-Ping Zhou, Jia Ni, Xiao-Chun Huang, and Dan Li*Abstract:By systematically varying the geometric length and electronic properties of the second ligating ligands of halogen (Cl
, Br
, and I
) and pseudohalogen (CN
, SCN
, and N3) anions, we synthesized 11 isomeric/isostructural copper(I) complexes: [Cu2(L3-3)I]n (1),[Cu2(L4-4)Br]n (2-Br), [Cu2(L4-4)Cl]n (2-Cl), [Cu2(L3-4)(CN)]n(3), [Cu2(L3-3)(CN)]n (4), [Cu3(L4-4)(CN)2]n (5), {[Cu2(L4-4)-Br]2 3 CuBr}n (6-Br), {[Cu2(L4-4

Shun-Ze Zhan, Mian Li, Xiao-Ping Zhou, Jun-Hao Wang, Ju-Rong Yang and Dan Li*Abstract:A supramolecular dual emissive system incorporating two classical copper(I)-cluster-based luminophores, namely, Cu4I4 and Cu3Pz3 (Pz = pyrazolate), is reported. The targeted luminescent coordination polymer exhibits reversible thermochromism spanning from green to orange-red.文章链接：c1cc14303d.pdf

Xiao-Ping Zhou, Zhengtao Xu,* Matthias Zeller, Allen D. Hunter, Stephen Sin-Yin Chui, and Chi-Ming Che.Abstract:We report dynamic, multiple single-crystal to single-crystal transformations of a coordination network system based on a semirigid molecule, TCPSB = 1,3,5-tri(40-carboxyphenylsulphonyl)benzene, which nicely balances shape persistence and flexibility to bring about the framework dynamics in the solid state. The networks here generally consist of (1) the persistent core component (denote

Da-Qian Feng, Xiao-Ping Zhou, Ji Zheng, Guang-hui Chen, Xiao-Chun Huang and Dan Li*Abstract:The reactions of CuBr2 with pyridyl 2,2′:6′,2′′-terpyridine ligands in methanol yielded four copper complexes under solvothermal conditions. The self-assembly processes were accompanied by designing bitopic precursor ligands and increasing the stoichiometric metal–ligand ratio. In the four resulting complexes, the pendant pyridyl groups of pyridylterpyridine were selectively in situ N-methylated and yield