Shun-Ze Zhan,* Fei Ding, Xiao-Wei Liu, Guo-Hui Zhang, Ji Zheng, and Dan Li*

Abstract: White-light emission with CIE (0.32, 0.34) was realized for an o-terphenyl (oTP) molecule in its Ag₃[3,5-(CF₃)₂Pz]₃ (Pz = pyrazolate) sandwiching adduct, originating from the hybrid of fluorescence and sensitized long-afterglow phosphorescence of oTP. Density functional theory (DFT) and time-dependent DFT calculations revealed that heavy-atom effects of Ag play a crucial role in sensitization of the triplet of oTP, giving off its ultralong phosphorescence.

文章链接：Inorg Chem 2019 12516.pdf