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Assembly of Metal-Organic Frameworks of SiF6 2- in Situ Formed from Borosilicate Glass

Meng-Ying Sun, Xue-Zhi Wang, Zi-Ye Chen, Xiao-Ping Zhou,* and Dan Li*



Abstract: The SiF62− anions are in situ formed in the reactions of MF2 (M = Cu2+, Zn2+, Ni2+, and Co2+) salts and nitrogen-containing ligands in borosilicate glass tubes under solvothermal conditions and then used to further construct a family of metal−organic frameworks (MOFs). This in situ reaction demonstrates a new and facile strategy for the fabrication of MOFs based on SiF62−.


文章链接:Inorg Chem 2019 12501.pdf