超分子配位化学研究所
Institute of Supramolecular Coordination Chemistry
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Control over the synthesis of homovalent andmixed-valence cubic cobalt-imidazolate cages

Liang Liang,‡b Dong Luo, ‡a Tao Zuo,a Xiao-Ping Zhou *a and Dan Li *

 


AbstractA series of cubic cobalt-imidazolate cages have been successfully synthesized via subcomponent self-assembly in different solvents under solvothermal conditions. The homovalent CoII and mixed-valence CoIII,II-imidazolate cages are assembled with control over the mixed solvent ratio of N,N-diethylformamide/ethanol, respectively.

 

文章链接:c9cc02083g.pdf