研究进展
A chemopalette strategy for white light by modulating monomeric and excimeric phosphorescence of a simple Cu(I) cyclic trinuclear unit
Hu Yang, ‡ab Ji Zheng, ‡a Su-Kao Peng, a Xiao-Wei Zhu, a Meng-Yan Wan,a Weigang Lua and Dan Li *a
Abstract: Room-temperature white phosphorescence with a quantum yield (QY) of 35.6% and a CIE coordinate of (0.33, 0.37) is observed for Cl-a, the crystal of cyclic Cu3(4-chloropyrazolate)3. Its white light consists of comparably uncommon monomeric blue and common excimeric yellow phosphorescence associated with Cu3(pyrazolate)3, achieved by multiple non-covalent interactions involving chlorine.
文章链接： 
C9CC00716D.pdf
