Xiao-Ping Zhou, Xuanjun Zhang, Shi-Hong Lin, and Dan Li*

Abstract: Reactions of AgX with 2,4,6-tri(2-pyridyl)-1,3,5-trazine (tpt) yielded three 3D highly symmetric isostructural coordination polymers (X ) ClO4-, BF4-, and PF6-) and a dimer (X ) CF3COO-), respectively. In the coordination polymers, anion-ð interactions are found between the multiatomic anions and tpt ligands. Systematic variation including synthetic methods, ratios of reactants, and solvents provides synthetic evidence proving that anion-ð interactions play a decisive role in assembly of the coordination polymers.

文章链接：cg0608256.pdf