学术报告
In Situ Formed Guanidinium Cations as Templates To Direct Fabrication of Honeycomb-like CuCN Networks
Shi-Hong Lin, Xiao-Ping Zhou, Dan Li,* and Seik Weng Ng
Abstract: The solvothermal reaction of CuSCN and 1,2-bis(diphenylphosphino)ethane (dppe) in mixed solvents acetonitrile/n-hexane/ (methanol or ethanol) gave a honeycomb-like guanidinium cyanocuprate [C(NH2)3)] · [Cu2(CN)3]. The in situ formed cations C(NH2)3+ act as templates to direct the formation of the CuCN network in which multiple weak N-H···N/C hydrogen interactions potentially exist between the cations C(NH2)3+ and the {CuCN}6 rings.
文章链接：
cg800262d.pdf
