研究进展
pH-Induced formation of metalloligand: increasing structure dimensionality by tuning number of ligand functional sites
Wen-Xiu Ni, Mian Li, Xiao-Ping Zhou, Zhen Li, Xiao-Chun Huang and Dan Li*
Abstract: Two complexes, 2D [Cu2(CN)2(4-Hpcih)]n and 3D{[Cu2(CN)1.5(4-pcih)]1.25H2O}n (4-Hpcih = 4-pyridinecarbaldehyde isonicotinoyl hydrazone), were obtained using a synthetic approach of pH-induced formation of metalloligands, successfully demonstrating a strategy to increase structuredimensionality by tuning the number of ligand functional sites.
文章链接:b705603f.pdf