Xiao-Ping Zhou, Zhengtao Xu,* Matthias Zeller, Allen D. Hunter, Stephen Sin-Yin Chui, Chi-Ming Che, and Jianhua Lin

Abstract: A silver(I) sulfide species is now imbedded in a porous coordination network. Such a composite system builds on the molecule tetrakis- (methylthio)-1,4-benzenedicarboxate that holds out the hard carboxylate to europium(III) to form a host net, while taking on AgCl using its soft sulfur side arms. AgCl is then treated with H2S to form the dark-colored Ag2S species, while leaving the hard host net intact and upstanding. This hard-soft duality serves to conjoin the rich electronic flavors of metal chalcogenides and the flexible textures of coordination nets.

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