Tian Wen, Mian Li, Xiao-Ping Zhou and Dan Li*

Abstract: The solvothermal in situ double cycloaddition reaction of 2- cyanopyrimidine, Cu2O and NaN3 with aqueous ammonia additive generated a two dimensional copper(I) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4- triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-triazolate ligands.

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