超分子配位化学研究所
Institute of Supramolecular Coordination Chemistry
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An in Situ Embedded Square-Planar CuII/NiIIN4 Metalloligand in Coordination Polymers for Visible-Light Photocatalysis

 Yun-Long Hou, Yunhong Pi, Xiao-Ping Zhou, and Dan Li*


Abstract: Three coordination polymers (CPs) with square-planar CuII/NiIIN4 subunits were formed in one step by subcomponent self-assembly, giving rise to an unprecedented linking variety of in situ embedded metalloligands and CuI clusters. All CPs exhibit unusual visible-light adsorption. Enhanced photocatalytic activity and high selectivity were observed in the oxidation of benzene under visible-light irradiation.


文章链接:acs.inorgchem.7b03068.pdf